Sienna's the picture of a 21st century woman

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The portrait of the 25-year-old actress will appear alongside those of TV presenters Richard and Judy, fashion designer Giles Deacon and film director Richard Curtis.

The photograph of the Factory Girl and Alfie star was originally taken by American photographer Valerie Phillips for the Nylon fashion magazine cover February edition.

It comes as Miller has been linked to American rapper P Diddy. The pair were recently seen together in the VIP room of the Paper nightclub following the Princess Diana memorial concert where Diddy performed. The pair have denied they are an item.

21st Century Portraits opens at the National Portrait Gallery on 22 July.