Angelina Jolie, Brad Pitt (and the baby bump) muck in with Clinton to clean up New Orleans

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Jolie and Brad Pitt took time out from Hollywood glamour to take part in charity work for the victims of hurricane Katrina.

The happy couple joined former president Bill Clinton for the 'Make a difference, make a commitment' Campaign in New Orleans.

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Looking swell: Pregnant Angelina Jolie and Brad Pitt with local resident Dee Carla Rogers on Lower 9th Ward in New Orleans on Sunday

Jolie showed off her growing baby bump, looking relaxed in a hippie-inspired maxi dress, as doting father-to-be Pitt helped the 600 volunteers clean up the neighbourhood devastated by Hurricane Katrina.

The massive project was organised by Pitt's Make it Right Foundation aided by the Clinton Global Initiative.

The actress is reportedly expecting twins, with sources saying she and partner Pitt are "absolutely ecstatic" at the prospect.

Twins will mean the couple will be parents to six children. The family currently consists of Maddox, 6, Pax, 4, Zahara, 3, and biological daughter Shiloh, 1.

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Giving back: Angelina and Brad pose with former residents of New Orleans

Helping hand: Brad and Bill Clinton get stuck in, cleaning up the area devastated by Hurricane Katrina