The singer introduced the trailer for the new James Bond film Quantum of Solace at the ceremony at the Royal Festival Hall.
But her diamante encrusted gown was the major attraction, clinging to her hour glass figure.
Frilly number: Kylie Minogue shimmered in a diamante encrusted lace dress at London's National Movie Awards
The Londoner teamed the silver and black strapless design with gold strappy sandals and bright red nails.
She is currently in the middle of intensive preparations for her upcoming X2008 tour to her native Australia.
And the hard work perfecting her dance routines is evidently paying off with her tiny waist and toned arms showing the benefits.
The singer also posed with Hollywood A lister Meryl Streep, with the actress' height highlighting Kylie's tiny frame.
How are you up there? Kylie Minogue smiles up at Meryl Streep
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You big softie
Gay marriage
